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    POLLUTION

    The Concept of Pollution
    Pollution can also be defined as the introduction of contaminants or pollutants into the natural environment. The environment comprises of living (biotic) and non-living (abiotic) things such as plants, animals, air, land and water.
    Contaminants or pollutants are harmful substances introduced into the environment that disturb the balance of nature. Pollution can be in the form of chemical substances or energy such as noise, heat or light.

    Human activities play a major role in the pollution of the environment. Humans engage in a myriad of activities such as agriculture, manufacturing, transport, waste disposal, mining etc. All of these activities contribute to environmental pollution in one way or another.

    There are three main types of pollution:
    • Terrestrial (land) pollution
    • Aquatic (water) pollution
    • Aerial (air) pollution

    Ozone Layer Destruction
    The Meaning of Ozone Layer and its Importance of to Life on Earth
    The atmosphere is divided into five layers. From the closest and thickest to the farthest and thinnest, the layers are: troposphere, stratosphere, mesosphere, thermosphere and exosphere.
    The majority of the atmosphere‟s ozone is in the stratosphere, which extends from 10 kilometres to 50 kilometres above the earth‟s surface.

    The ozone layer is a layer of gaseous ozone (O3) in the stratospheric atmosphere. The earth‟s stratospheric ozone plays an important role in absorbing ultraviolet radiations. Ultraviolet radiations (UVR), are high energy electromagnetic waves emitted from the sun. UV radiations include UV-A, the least dangerous form of UV radiations, UV-B, and UV-C, which is the most dangerous. UV-C is unable to reach the earth's surface due to stratospheric ozone's great ability to absorb it. The real threat comes from UV-B, which can enter the earth's atmosphere, and has adverse effects.
    UV-B radiation (the higher-energy UV) causes skin cancer, eye cataracts, and can lead to genetic damage.Although natural phenomena can cause temporary ozone loss, chlorine and bromine released from man-made compounds such as CFCs are the main cause of ozone layer depletion (destruction). They are also greenhouse gases and contribute to global warning.

    CFCs are made up of chlorine, fluorine and carbon atoms and are more extremely stable. This extreme stability allows the CFCs to slowly make their way into the stratosphere. They can remain in the atmosphere for 20 to 120 years or more.
    In the stratosphere, CFCs are broken down by UV rays from the sun, releasing free chlorine radicals (•Cl). Chlorine atom (radical) reacts with an ozone molecule (O3) to form chlorine monoxide, ClO, and one molecule of oxygen (O2). Then chlorine monoxide reacts with a second molecule of ozone to yield the original chlorine atom and two molecules of oxygen.
    • 1. CCl3F → •CCl2F + •Cl2.
    • •Cl + O3 → •ClO + O23.
    • •ClO + O3 → •Cl + 2O2
    After each reaction, the freed chlorine atom (radical) is able to begin destructive cycle again with another ozone molecule. It is estimated that one chlorine radical can destroy up to 100,000 molecules of ozone.

    Chemical Substances which Destroy the Ozone Layer
    The main ODS are chlorofluorocarbons (CFCs), hydrochlorofluorcarbons (HCFCs), carbon tetrachloride and methyl chloroform. Halons (brominated fluorocarbons) also play a big role. Their application is quite limited: they're used in specialized fire extinguishers. But the problem with halons is they can destroy up to 10 times as much ozone as CFCs can.
    Hydrofluorocarbons (HFCs) are being developed to replace CFCs and HCFCs, for uses such as vehicle air conditioning. HFCs do not deplete ozone, but they are strong greenhouse gases. CFCs are even more powerful contributors to global climate change, though, so HFCs are still the better option until even safer substitutes are discovered. The following are the main ozone-depleting substances:
    Chlorofluorocarbons (CFCs)
    • The most widely used ODS, accounting for over 80% of total stratospheric ozone depletion.
    • Used as coolants in refrigerators, freezers and air conditioners in buildings and cars manufactured before 1995.
    • Found in industrial solvents, dry-cleaning agents and hospital sterilizers.
    • Also used in foam products such as soft-foam padding (e.g. cushions and mattresses) and rigid foam (e.g. home insulation)
    Halons
    • Used in some fire extinguishers, in cases where materials and equipment would be destroyed by water or other fire extinguisher chemicals.
    Trichloroethane (CH3CCl3)
    • Used mainly in industry as a solvent in many products and for metal cleaning.
    Carbon tetrachloride (CCl4)
    • Used in solvents and some fire extinguishers.
    Hydrochlorofluorocarbons (HCFCs)
    • HCFCs have become major, “transitional” substitutes for CFCs. They are much less harmful to stratospheric ozone than CFCs are. However, HCFCs still cause some ozone destruction and are potent greenhouse gases.
    Possible effects of ozone depletion
    As ozone depletes in the stratosphere, it forms a 'hole' in the layer. This hole enables harmful ultraviolet rays to enter the earth's atmosphere. Ultraviolet rays of the sun are associated with a number of health-related and environmental issues. Let us take a look at how ozone depletion affects different life forms.

    Impact on humans
    Skin cancer: Exposure to ultraviolet rays poses an increased risk of developing several types of skin cancers, including malignant melanoma, basal and squamous cell carcinoma.

    Eye damage: Direct exposure to UV radiations can result in photokeratitis (snow blindness), and cataracts.

    Immune system damage: Increased exposure to UV rays may lead to impairment of the immune system.

    Accelerated aging of skin: Constant exposure to UV radiation can cause photo allergy, which results in the outbreak of rash in thin-skinned people.

    Other effects: Ozone chemicals can cause difficulty in breathing, chest pain, throat irritation, and can hamper lung functioning.

    Effects on amphibians
    Ozone depletion is listed as one of the causes of the declining numbers of amphibian species. Ozone depletion affects many species of amphibians at every stage of their life cycle. Some of the effects are mentioned below:
    • Hinders growth and development in larvae.
    • Changes behaviour and habits.
    • Causes deformities in some species.
    • Decreases immunity: Some species have become more vulnerable to diseases and death.
    • Retinal damage and blindness in some species.
    Effects on marine ecosystems
    In particular, plankton (phytoplankton and bacterioplankton) are threatened by increased UV radiation. Marine phytoplankton play a fundamental role in both the food chain as well as the oceanic carbon cycle. Plankton play an important role in converting atmospheric carbon dioxide into oxygen. Ultraviolet rays can influence the survival rates of these microscopic organisms, by affecting their orientation and mobility. This eventually disturbs and affects the entire ecosystem.

    Impact on plants
    In some species of plants, UV radiation can alter the time of flowering, as well as the number of flowers. Plant growth can be directly affected by UV-B radiation. Despite mechanisms to reduce or repair these effects, physiological and developmental processes of plants are affected.

    Methods of Protecting the Ozone Layer
    Suggest methods of protecting the ozone layer
    The most effective way of controlling the depletion of ozone layer is to ban the production and use of ozone depleting substances (ODS). The most dangerous of these substances are chlorofluorocarbons (CFCs). Since their introduction, CFCs have been used as:
    • refrigerants in refrigerator and air conditioning units;
    • propellants in aerosol cans;
    • solvents and blowing agents for insulation foams;
    • cleaners in electronic industry;
    • fire extinguisher chemicals.
    Eliminating the use of CFCs will prevent the depletion of ozone layer. New refrigerants have been developed and new aerosols use other propellants such as methane in place of CFCs.